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A near 100% initiation efficiency and 100% regioselectivity at the methylacrylic C═C bond was realized by bulky Lewis pairs-mediated polymerization of polar divinyl monomers such as 4-vinylbenzyl ...

The mechanism of polymer chain growth at the Phillips catalyst has been studied, with the three prevailing mechanistic proposals, the Cosee−Arlman, Green−Rooney, and metallacycle mechanisms, ...